A student plans a two-step synthesis of 1-ethyl-3-nitrobenzene from benzene. The first step is nitration of benzene to give nitrobenzene, and the second step is a Friedel-Crafts alkylation using CH3CH2Cl and AlCl3. The plan is flawed because: A : When the alkyl halide interacts with AlCl3, the resulting carbocation can rearrange before it has a chance to react with the aromatic ring. B : Nitrobenzene is too deactivated (by the nitro group) to undergo a Friedel-Crafts alkylation. C : The nitro group will direct the incoming alkyl group para position, rather than to the meta position. D : A blocking group is required to achieve this synthesis.

Answers

Answer 1

Answer:

Nitrobenzene is too deactivated (by the nitro group) to undergo a Friedel-Crafts alkylation.

Explanation:

The benzene ring in itself does not easily undergo electrophilic substitution reaction. Some groups activate or deactivate the benzene ring towards electrophilic substitution reactions.

-NO2 ia a highly deactivating substituent therefore, Friedel-Crafts alkylation of nitrobenzene does not take place under any conditions.

This reaction scheme is therefore flawed because Nitrobenzene is too deactivated (by the nitro group) to undergo a Friedel-Crafts alkylation.


Related Questions

Rick is creating a love potion for Morty. To make the potion, Rick's needs 51 mL of a mixture solution where 40% is carbonated water. After checking around his shop, Rick finds two solutions he could use. The first solution he found is 65% green tea, 15% carbonated water, and 20% whole milk. The second solution is 17% orange juice, 38% lemonade, and 45% carbonated water. How much of the first solution and second solution does Rick need to mix together to create the love potion? Round your final answers to one decimal place. You may solve this problem using any method we have learned in the class.

Answers

Answer:

The amount of the first solution rick needs to mix together to create the love portion is 8.5 mL

Explanation:

So as to make the love potion, we have;

The percentage of carbonated water in the love portion = 40%

The percentage of green tea in the first solution = 65%

The percentage of carbonated water in the first solution = 15%

The percentage of whole milk in the first solution = 20%

The percentage of orange juice in the second solution = 17%

The percentage of lemonade in the second solution = 38%

The percentage of carbonated water in the second solution = 45%

Let 'x' represent the volume in mL of the first solution added to make the love portion, and let 'y' be the volume in mL of the second solution added to make the love portion, we have;

x + y = 51...(1)

0.15·x + 0.45·y = 0.40×51 = 20.4

0.15·x + 0.45·y = 20.4...(2)

Solving the system of simultaneous equation by making 'y' the subject of each of the equation gives;

For equation (1)

y = 51 - x

For equation (2)

y = 20.4/0.45 - (0.15/0.45)·x = 136 - 3·x

y = 136/3 - (1/3)·x

Equating the two equations of 'y', gives;

51 - x = 136/3 - (1/3)·x

51 - 136/3 = x - (1/3)·x

17/3 = (2/3)·x

(2/3)·x = 17/3

x = (3/2) × (17/3) = 17/2 = 8.5

x = 8.5

y = 51 - x = 42.5

y = 42.5

Therefore, the amount of the first solution rick needs to mix together to create the love portion, x = 8.5 mL

HELPPP PLZZZZ NOWWW !!!!!!!

Answers

It would be B. Reactions are slower when there is a lower concentration, because for the boat with lower concentration it took wayyy longer to decay then the one with high concentration.

What would be the mass in amu of 150 atoms of carbon?

Answers

Answer:

Do you mean the periodic table? The atomic mass of carbon is 12 and oxygen is 16.

If I understand you right though, what you’re looking for is what oxygen’s mass would be in a certain unit of measurement with which carbon weighs 150 units.

In regular atomic mass units carbon’s mass is 12 and oxygen’s is 16, so oxygen’s mass is 4/3 times carbon’s mass. In our new unit of measurement where carbon weights 150 units, oxygen would weigh 150 * 4/3 = 200 units.

is clorox an acid or base? ​

Answers

Answer:

Chlorine bleach is strongly basic. We actually make it by dissolving chlorine gas in a concentrated solution of sodium hydroxide, which forms sodium hypochlorite and sodium chloride, in the following equilibrium.

Explanation:

BTS ARMY

I need help with this chem problem!

Answers

sorry i’m taking chem next year so i can’t answer it but don’t press the link that the other person gave u. i think it tracks ur location

You want to decaffeinate your coffee by extracting the caffeine out with dichloromethane (they don't do it that way anymore, but they used to). It's too late to extract the caffeine from the coffee beans, because you've already brewed yourself a 200 mL cup of coffee. Your particular brand of coffee contains 100 mg of caffeine in that 200 mL cup. The partition coefficient of caffeine in dichloromethane/water is 9.0 (it is more soluble in the dichloromethane).
How much caffeine would still be in your 200 mL if you did:_____.
A. One extraction using 200 mL ofdichloromethane
B. Two extractions using 100 mL ofdichloromethan each.

Answers

Solution :

Partition coefficient Kd

[tex]$=\frac{\frac{\text{mass of caffeine in } CH_2Cl_2}{\text{volume of } CH_2Cl_2}}{\frac{\text{mass of caffeine in water}}{\text{volume of water}}}$[/tex]

= 9.0

A). 1 x 200 mL extraction :

Let m be the mass of caffeine in the water

Mass of caffeine in [tex]$CH_2Cl_2$[/tex] = 100 - m

[tex]$\frac{\frac{100-m}{200}}{\frac{m}{200}} = 9.0$[/tex]

[tex]$=\frac{100-m}{m} = 9.0$[/tex]

[tex]$= 10 m = 100$[/tex]

m = 10

Mass remaining in coffee = m =  10 mg

B). 2 x 100 mL extraction :

First extraction :

Let [tex]$m_1$[/tex] be the mass of caffeine in the water

Mass of caffeine in [tex]$CH_2Cl_2$[/tex] = [tex]$100-m_1$[/tex]

[tex]$\frac{\frac{100-m_1}{100}}{\frac{m_1}{200}} = 9.0$[/tex]

[tex]$=\frac{100-m_1}{m_1} = 4.5$[/tex]

[tex]$ 5.5 \ m_1 = 100$[/tex]

[tex]$m_1$[/tex]  = 18.18

Mass remaining in coffee = [tex]$m_1$[/tex] =  18.18 mg

Second Extraction :

Let [tex]$m_2$[/tex] be the mass of caffeine in the water

Mass of caffeine in [tex]$CH_2Cl_2$[/tex] = [tex]$18.18-m_2$[/tex]

[tex]$\frac{\frac{18.18-m_2}{100}}{\frac{m_2}{200}} = 9.0$[/tex]

[tex]$=\frac{18.18-m_2}{m_2} = 4.5$[/tex]

[tex]$ 5.5 \ m_2 = 18.18$[/tex]

[tex]$m_2$[/tex]  = 3.3

Mass remaining in coffee = [tex]$m_2$[/tex] =  3.3 mg

PLEASE HELP ME!!! i have no idea how to answer these!

Answers

Answer: Im answering this for points

DONT COME ON MY STUFF SAYING THAT I GOT SCHOOL TO DO JUST LIKE YOU AND YOUR GIVING ME IRRELEVANT ANWSERS JUST TO GET POINTS? THATS A WASTE OF MY TIME

Explanation:

Please answer by the number ! I will mark any correct answer brainliest :)

Answers

Answer:

36 joules is the answer

1/2mv^2

1/2* 8*3*3

4*9

36joules

Tris is a molecule that can be used to prepare buffers for biochemical experiments. It exists in two forms: Tris (a base) and TrisH (an acid). The MW of Tris base is 121.14 g/mol; the MW of TrisH is 157.6 g/mol (the extra weight is due to the Cl- counterion that is present in the acid). The Ka of the acid is 8.32 X 10-9. Assume that you have TrisH in solid form (a powder), unlimited 1M HCl, unlimited 1 M NaOH and an unlimited supply of distilled water. How would you prepare 1 L of a 0.02 M Tris Buffer, pH

Answers

Solution :

The reaction :

[tex]$\text{TrisH}^+ + \text{H}_2\text{O} \rightarrow \text{Tris}^- +\text{H}_3\text{O}^+$[/tex]

We have

[tex]$K_a = \frac{[\text{Tris}^-]\times[\text{H}_3\text{O}^-]}{[\text{TrisH}^+]}$[/tex]

     [tex]$=\frac{x^2}{0.02-x}$[/tex]

     [tex]$= 8.32 \times 10^{-9}$[/tex]

Clearing x, we have [tex]$x=1.29 \times 10^{-5}$[/tex] moles of acid

Now to reach pH = [tex]$7.8 (\text{ pOH} = 14-7.8 = 6.2)$[/tex], we must have an [tex]$OH^-$[/tex] concentration of

[tex]$[OH^-] = 10^{-pOH}$[/tex]

          [tex]$=10^{-6.2}$[/tex]

         [tex]$=6.31 \times 10^{-7}$[/tex] moles of base

We must add enough NaOH of 1 M to neutralize the acid calculated above and also add the calculated base.

[tex]$n \ NaOH = 1.29 \times 10^{-5} + 6.31 \times 10^{-7}$[/tex]

               [tex]$=1.35 \times 10^{-5}$[/tex] moles

Vol [tex]$NaOH = 1.35 \times 10^{-5} \text{ moles} \times \frac{1000 \ mL}{1 \ mol}$[/tex]

                 = 0.0135 L

Tris mass [tex]$H^+ = 0.02 \text{ mol} \times 157.6 \ g/mol$[/tex]

                        = 3.152 g

To prepare the said solution we must mix

-- [tex]$3.152 \ g \text{ TrisH}^+$[/tex]

-- [tex]$0.0135 \ mL \ NaOH \ 1M$[/tex]

-- [tex]$\text{Gauge to 1000 mL with H}_2\text{O}$[/tex]

how many significant digits are in the number 1.0 × 10^3?​

Answers

121837481817381813727-
answer: 1000
1•10^3 add three 0’s

Elizabeth REALLY didn’t study, and she also wrote the formula for dicarbon tetrafluoride as “C2F5”. Describe why her answer is incorrect.

Answers

Answer:

correct formula: C2F4

Explanation:

tetra means 4. There are 2 C and 4 F in dicarbon tetrafluoride.

need help whoever answers will be awarded branliest answer ​

Answers

Answer:

1.used to seperate solids from liquids, and is a act of pouring a mixture onto a membrane this allows the passage of liquid and results in the collection of a solid

2. the solution would passed through without losing and solids

3 would allow them to dry or on further hearing decompose

Explanation:

help please guys i need it

Answers

Answer:

Amplitude

Explanation:

Hope I helped :)

What does the article “Absolute Zero” tell us about what temperature really means?

Answers

Answer:

Absolute zero, technically known as zero kelvins, equals −273.15 degrees Celsius, or -459.67 Fahrenheit, and marks the spot on the thermometer where a system reaches its lowest possible energy, or thermal motion. There's a catch, though: absolute zero is impossible to reach.

Explanation:

A cylinder of oxygen (O2) gas at STP has a volume of 2.75 L. How many oxygen molecules does it contain?

Answers

Answer:

7.40×10²² molecules.

Explanation:

From the question given above, the following data were obtained:

Volume of oxygen = 2.75 L

Number of molecules of oxygen =?

Next, we shall determine the number of mole of oxygen present. This can be obtained as follow:

22.4 L contains 1 mole of oxygen at STP.

Therefore, 2.75 L will contain = 2.75 / 22.4 = 0.123 mole of oxygen at STP.

Finally, we shall determine the number of molecules of oxygen present. This can be obtained as follow:

From Avogadro's hypothesis:

1 mole of oxygen = 6.02×10²³ molecules

Therefore,

0.123 mole of oxygen = 0.123 × 6.02×10²³

0.123 mole of oxygen = 7.40×10²² molecules.

Thus, the cylinder contains 7.40×10²² molecules of oxygen.

GIVING 21 POINTS AWAY PLEASE HELP ME WITH BOTH QUESTIONS ASAP!!!!

Answers


I think question 1 is B
And question 2 is also B

What enzyme catalyses the reaction of PRPP transfer to hypoxanthine with
formation of IMP?

Answers

Answer:

HPRT

Explanation:

HPRT catalyzes the salvage reactions of hypoxanthine and guanine with PRPP to form IMP and GMP

The formation of GMP from IMP requires oxidation at C-2 of the purine ring, followed by a glutamine-dependent amidotransferase reaction that replaces the oxygen on C-2 with an amino group to yield 2-amino,6-oxy purine nucleoside monophosphate, or as this compound is commonly known, guanosine monophosphate.

Who among, Amit and Saaketh, is correct? Explain.​

Answers

Answer:

What is their question answers exactly? I won't be able to explain who is correct.

Explanation:

Answer:

Not a lot to draw from this question if im going to be honest

Explanation

(80 points)
Requirements
You must include each of the following in your diagram, story/explanation:
1. precipitation
2. runoff
3. evaporation
4. condensation
5. transpiration
6. infiltration
7. groundwater
8. clouds
9. collection areas (example: ocean or lake)
Instructions
1. Complete either the diagram or written explanation – 10 points
• Diagram – you will draw the water cycle process. You must include each of the required items and label each. You are not required to color it, but it is encouraged to help differentiate between the processes.
• Written Explanation – for either of these options you need to include each of the processes. It may be beneficial to explain them in the order in which they occur but is not necessary.
2. Answer the questions


Questions
1. What process drives evaporation and transpiration? Explain how this process operates in the water cycle? (2 Points)


2. What role does gravity play in the water cycle? Hint: it is in more than 1 process (2 Points)


3. What states of matter will your find water in going through the water cycle? (1 Point)

Answers

Answer:

1.solar energy drives the cycle by evaporating water from its source and water moves from plants by the process of transpiration

2. in precipitation because the water falls from the sky

3.liquid and gas

Which postmortem parameter is fixed by 8 hours?

1)cloudiness of the eyes

2)rigor mortis

3)livor mortis

4)putrefaction

Answers

The postmortem cooling or algor mortis gets fixed by 8- 10 hours after death. The temperature of the body after death can be used to determine the time since death.


If 280.4 g of KOH react with an excess of FeCl3, how many grams of Fe(OH)3 will be produced?
FeCl3 + 3 KOH — Fe(OH)3 + 3 KCI
How many grams will be produced?

Answers

Answer:

From 00:11

Balance the Molecular Equation

From 01:35

Ions for the Complete Ionic Equation

From 03:04

Net Ionic EquationExplanation:

How are fossil fuels formed from geologic processes?

Answers

Answer:

Explanation:

Fossil fuels are hydrocarbons, namely, petroleum , coal and natural gas, formed from buried combustible geologic deposits of organic and natural materials. They are created from decayed animals and plants that convert into coal, crude oil or heavy oil due to constant exposure to pressure and heart in the earth’s crust.

The compounds that make up plankton and plants convert into fossil fuels. Plankton decomposes into natural gas and oil, while plants become coal. Nowadays, humans extract these resources through coal mining and the drilling of oil.

What are fossil fuel ?

The term fossil fuel is defined as they are made from decomposing plants and animals. An example of a fossil fuel is coal, as well as oil and natural gas.

Because they were generated from the petrified, buried remains of plants and animals that once lived millions of years ago, coal, crude oil, and natural gas are all referred to as fossil fuels.

Thus, The remains of these animals underwent a transformation into what we now know as fossil fuels over millions of years at great pressure and high temperature.

To learn more about the fossil fuel, follow the link;

https://brainly.com/question/2029072

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A 497.9-gallon steel storage tank contains 91.7kg of methane. If the temperature is 23.7˚C what is the pressure inside the tank?

Answers

Answer:

74.08 atm

Explanation:

We'll begin by converting 91.7 kg to grams (g). This can be obtained as follow:

1 kg = 1000 g

Therefore,

91.7 kg = 91.7 kg × 1000 g / 1 kg

91.7 kg = 91700 g

Next, we shall determine the number of mole present in 91700 g of methane, CH₄. This can be obtained as follow:

Mass of CH₄ = 91700 g

Molar mass of CH₄ = 12 + (4"1)

= 12 + 4

= 16 g/mol

Mole of CH₄ =?

Mole = mass /Molar mass

Mole of CH₄ = 91700 / 16

Mole of CH₄ = 5731.25 moles

Next, we shall convert 497.9 gallon to litres (L). This can be obtained as follow:

1 gallon = 3.785 L

Therefore,

497.9 gallon = 497.9 × 3.785

497.9 gallon = 1884.55 L

Next, we shall convert 23.7 ˚C to Kelvin temperature. This can be obtained as follow:

T(K) = T(˚C) + 273

T(˚C) = 23.7 ˚C

T(K) = 23.7 °C + 273

T(K) = 296.7 K

Finally, we shall determine the pressure in the tank as follow:

Number of mole (n) = 5731.25

Volume = 1884.55 L

Temperature (T) = 296.7 K

Gas constant (R) = 0.0821 atm.L/Kmol

Pressure (P) =?

PV = nRT

P × 1884.55 = 5731.25 × 0.0821 × 296.7

P × 1884.55 = 139607.92

Divide both side by 1884.55

P = 139607.92 / 1884.55

P = 74.08 atm

Therefore the pressure in the tank is 74.08 atm

Carbon dioxide ( a greenhouse gas) is breathed out by billions of people all over the world? Yes or no

Answers

Answer:

yes

Explanation:

Answer:

yes

Explanation:

Humans inhale oxygen and breath out carbon dioxide.

Assume that the ratio of moles of Cl to moles of Cu are 2.39. If we can represent the formula by CuClx, what is the value for x? Round your answer to the nearest whole number. Do NOT include units. So, if you think the formula is CuCl6, you enter the number 6.

Answers

Answer:

x=2.

Explanation:

Hello there!

In this case, since we have a mole ratio of moles of Cl to moles of Cu as 2.39, it is possible to write the following:

[tex]\frac{2.39molCl}{1molCu}[/tex]

Thus, since the two possible copper chlorides are CuCl and CuCl₂, we can therefore infer that x=2 since it is close but not as close as it should to the whole number 2.

Best regards!

How do the polar easterlies and the jet stream work together to affect the
weather in the United States?

Answers

Answer:

they can carry cold arctic air, producing snow and freezing weather.

Explanation:

-w- hope it helps

Who knows how to do this please help

Answers

Answer: You forgot to zero the balance

Explanation:

3. Explain what would happen to the digestion process if enzymes were not present. SC.6.L.14.5​

Answers

Without enzymes the nutrients in your food would go to waste which leads to a poor digestion and malnutrition. It’s because enzymes break down the nutrients which use it for energy

helppppppppppppppppp​

Answers

Answer:

b

Explanation:

After you set up your apparatus for the second part of the experiment, your group begins to add the textbooks on top of the plunger. It appears that the plunger continues to drop with every added book and does not return to its original place after the books are removed. What possible sources of error could be given for this experimental outcome? Be specific and give at least two reasons.

Answers

The possible sources of error that could be given for this experimental outcome is the change in the density of the air.

What is an experiment?

An experiment simply means the procedure that is carried out in order to refute a particular hypothesis. It should be noted that experiments are important to provide insights into the cause and effect of a particular situation.

In this situation, with every added book, the volume of that air column will reduce. It is just important that the temperature should remain constant when the gas compression is taking place.

Another source of error is the assumption of moles that was assumed was constant during the experiment. In this scenario, it's possible that some gas could have escaped while the compression was taking place.

Learn more about experiments on:

brainly.com/question/17274244

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