The partial pressure of each gas in the mixture is 376 mm of Hg for both respectively.
Partial pressure is the force that a fuel exerts. The sum of the partial pressures in a combination of all of the gases equals the overall stress. The strain exerted with the aid of an character fuel in a mixture is known as its partial strain.
The partial pressure of an individual gas is same to the whole pressure improved with the aid of the mole fraction of that gas. because it is established completely on the wide variety of particles and no longer the identification of the gasoline, the correct fuel Equation applies just as well to combinations of gases because it does to pure gases.
Partial pressure is extremely essential in predicting the movement of gases. do not forget that gases generally tend to equalize their strain in two areas which are related. A gas will pass from a place in which its partial strain is higher to a place wherein its partial stress is lower
Calculation:-
Total pressure = 752 mm hg
carbon dioxide = 6.03 g
mole = 6.03/44
= 0.14
mass of Oxygen = 4.37
moles = 4.37/32
= 0.14
total = 0.28
partial pressure of oxygen = 0.14/0.28 × 752 mm
= 376 mm of Hg
Partial pressure of Carbondioxide = 376 mm of Hg
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Place the following events in order starting with the vibration of the oval window and ending with the depolarization of hair cells.a. Increased pressure in perilymph of scala vestibulib. Pressure wave depresses basilar membranec. Inner hair cells move closer to tectorial membraned. Stereocilia bende. Tip-link proteins open K+ channelsf. K+ ions enter hair cells causing depolarization
The question mentions the Oval window in the human ear. The vibration of oval window and ending with the depolarization of hair cells have a particular order.
The oval window is a connective tissue membrane located at the end of the middle ear and the beginning of the inner ear.
The following events in order starting with the vibration of the oval window and ending with the depolarization of hair cells are given:
1) Oval window vibrates or tip-link proteins open K+ channels
2) Increased pressure in the perilymph of scala vestibuli
3) Pressure wave depresses basilar membrane
4) Inner hair cells move closer to the tectorial membrane
5) Stereocilia bend
6) K+ ions enter hair cells causing depolarization
Therefore, the vibration of oval window and ending with the depolarization of hair cells have a particular order.
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What is the effect of increasing concentration of Cu2+ and zn2+ on E cell?
As [Zn 2+] molar concentration increases, the E cell decreases. (Solvent of zinc sulphate) With a rise in [Cu 2+] molar concentration, the E cell grows. at various electrolyte concentrations, results.
A solute's molar concentration is the quantity of that solute in one unit of a solution. It can be measured in mol/L, mol/dm 3, or mol/m3. Molar concentration, also called molarity, is indicated by the letter M, or molar. Analyzing the health claims made for sports drinks and providing an overview of electrolytes. In chemistry and physics, an electrolyte is a material that conducts electricity after splitting into positively and negatively charged particles known as ions. Weak Electrolytes: Electrolytes that have not been fully dissolved into the solution.
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which compound(s) would be the major product(s) if you were to perform an eas nitration of phenyl acetate?
Para product .In organic reactions, multiple substituents can bind with the aromatic ring and according to the number of substituents; we get the mono/di/tri-substituted products.
In phenyl acetate, there is an acetate group present on the benzene ring. Phenyl acetate will undergo nitration reaction to form ortho and para products, as acetate group is an electron donating group. The para product will be the major product as it involves lesser steric hinderance. Phenyl acetate is the ester of phenol and acetic acid. It can be produced by reacting phenol (Which can be produced by decarboxylation of aspirin with acetic anhydride or acetyl chloride.Phenyl acetate can be separated into phenol and an acetate salt, via saponification: heating the phenyl acetate with a strong base, such as sodium hydroxide, will produce phenol and an acetate salt (sodium acetate, if sodium hydroxide were used.
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Identify the final concentrations of each species following the addition of 1. 0 m koh to a 2. 0 m hf solution.
The final concentration of KOH, HF and KF are 0 M, 1.0 M and 1.0 M respectively.
Chemical reaction:HF ( aq ) + KOH ( aq ) ⟶ KF ( aq ) + H₂O ( l )
Initial conc. 2.0 M 1.0 M 0 M
Final conc. 1.0 M 0 M 1.0 M
When 1.0 M KOH reacts with 2.0 M HF, 1.0 M KOH fully reacted.
we used unity method 1 M KOH = 1 M HF
so 1.0 M KOH reacts with 1.0 M HF to form 1.0 M KF
1.0 M HF remains unreacted.
Therefore, the final solution contains 1.0 M HF and 1.0 M KF. This means that the solution contains equal amounts of weak acid and salt.
Therefore, the final concentrations of KOH, HF, and KF are 0 M, 1.0 M, and 1.0 M, respectively.
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What documents provide information about chemicals used in lab and where can these documents be found?
SDS documents provide information about chemicals used in the lab and where can these documents be found
An SDS is a crucial document that details the risks, safety precautions, and emergency procedures for a specific chemical-containing product. Should overexposure occur, an SDS also describes the appropriate medical or first aid care. The product provider provides SDSs, which are created by the manufacturer.
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draw the major organic product of the reaction. be sure to draw both the wedge and hash bonds per stereocenter to fully convey the stereochemistry.
Gabriel synthesis produces primary amine through an SN2 reaction.
A primary amine is produced by the Gabriel synthesis using the SN2 reaction. Phthalimide is first deprotonated using a base to form a nucleophile. The original structure is inverted due to the negatively charged N attacking the alkyl halide from behind. Acid hydrolysis, base hydrolysis, or the application of hydrazine are all methods for liberating the main amine. The S configuration of the alkyl halide reactant is present. Gabriel synthesis involves an SN2 reaction,
Hence, the main alkyl amine product will be configured as R.
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which of the following correctly describes an ideal gas? multiple choice question. a gas that obeys the gas laws under all conditions a gas that suits a particular application perfectly a gas that is classified as a noble gas a gas that flows like a liquid
Among the options that correctly describes an ideal gas is a gas that obeys the gas laws under all conditions.
Ideal gas, also known as perfect gas, is a gas that physically complies with the ideal, or general, gas law, a particular idealised relationship between pressure, volume, and temperature. This law states that for a given amount of gas, the sum of the volume V and pressure P is proportional to the absolute temperature T; in equation form, PV = kT, where k is a constant. It is a generalisation that includes both Boyle's law and Charles's law as special cases. Such a relationship is known as a substance's equation of state, and it is sufficient to explain its basic behaviour. The kinetic theory of gases, which makes the assumptions, can be used to derive the ideal gas law.
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If the density of your unknown liquid is 0.65 g/mL, calculate the volume in liters that 3 mL of your unknown liquid would occupy when vaporized at the barometric pressure and temperature of your boiling water bath in Run 1. Use the accepted molar mass of your suspected unknown.unknown molar mass is 60g/mol
The volume of 3 mL evaporated unknown liquid is calculated to be 1.95 / 30.688 × Molar Mass
The volume in liters that 3 ml of the unknown liquid would occupy when vaporized can be calculated as follows;
as the boiling pressure at 1 atm is 100°C or 373°K and the standard STP temperature = 273°K and STP volume = 22.4 L
first, we calculate the temperature of the unknown as follows;
T = 373 °K ÷ 273°K
T = 1.37 °K
Density = D = 0.65 g/mL
So,
volume = volume of unknown liquid × D / molar mass × V × T
volume = 3 × 0.65 / molar mass × 22.4 × 1.37
volume = 1.95 / 30.688 × molar mass
Therefore the volume of 3 mL of the unknown liquid by using the accepted molar mass is 1.95 / 30.688 × molar mass
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PLEASE HELP ME!
What is the highest occupied molecular orbital fo nitrogen gas (Ny)? In other words, when you draw out the molecular orbital diagram for gaseous nitrogen, what is the highest molecular orbital that has electrons in it?
The highest occupied molecular orbital for nitrogen is 2pπ. In the ground state, there are two electrons present.
What does "highest occupied molecular orbital" refer to?
The highest-occupied molecular orbital for carbon monoxide (CO) is an electron-dense molecular orbital that surrounds the carbon atom. Pi orbitals are the lowest available molecular orbital for CO. The CO molecule's non-bonding molecular orbitals exhibit some minor bonding.
What is the highest electron shell that is occupied?
The valence shell is the highest populated electron shell, and the electrons that inhabit this shell are referred to as valence electrons. The electron configurations of the elements are reflected in their chemical characteristics.
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The highest occupied molecular orbital for nitrogen is 2pπ. In the ground state, there are two electrons present.
What does "highest occupied molecular orbital" refer to?The highest-occupied molecular orbital for carbon monoxide (CO) is an electron-dense molecular orbital that surrounds the carbon atom. Pi orbitals are the lowest available molecular orbital for CO. The CO molecule's non-bonding molecular orbitals exhibit some minor bonding.
What is the highest electron shell that is occupied?The valence shell is the highest populated electron shell, and the electrons that inhabit this shell are referred to as valence electrons. The electron configurations of the elements are reflected in their chemical characteristics.
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a 30.0-g sample of water at 280. k is mixed with 50.0 g of water at 330. k. calculate the final temperature of the mixture assuming no heat loss to the surroundings.
The final temperature of the mixture assuming no heat loss to the surroundings is 311.25 K.
The final temperature of the water mixture is calculated by, T(final) = (m1 T1 + m2 T2) / (m1 + m2), where m1 and m2 are the weights of the water in the first and second containers, T1 is the temperature of the water in the first container, and T2 is the temperature of the water in the second container.
Let the final temperature be 'T' k
heat lost by 50 g water = heat gained by 30 g water
50*C*(330-T) = 30*C*(T-280)
50*(330-T) = 30*(T-280)
16500 - 50*T = 30*T - 8400
80*T = 24900
T = 311.25 K
Therefore, the final temperature of the mixture is 311.25 K.
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a mixture of 10.0 g of ne and 10.0 g ar has a total pressure of 1.6 atm. what is the partial pressure of ne? a) 1.1 atm b) 0.80 atm c) 0.54 atm d) 0.40 atm e) 1.3 atm
The partial pressure of ne 1.1 atm, hence the Correct Option is a).
Solution:
partial pressure of Ne = mole fraction x total pressure
10/20 / 10/20+ 10/40 = 0.6875
partial pressure of Ne = 1.6 x 0.6875 = 1.1 atm
or
Moles of Ne = 10/20 = .5 moles
Moles of Ar = 10/40 = .25 moles
Partial pressure of Ne = .5*1.6/.75 = 1.06 nearly equal to = 1.1 atm
The partial pressure of a gas is a measure of thermodynamic activity of the gas's molecules.
In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. The total pressure of an ideal gas mixture is the sum of the partial pressures of the gases in the mixture (Dalton's Law).
The partial pressure of a gas is a measure of thermodynamic activity of the gas's molecules. Gases dissolve, diffuse, and react according to their partial pressures but not according to their concentrations in gas mixtures or liquids. This general property of gases is also true in chemical reactions of gases in biology. For example, the necessary amount of oxygen for human respiration, and the amount that is toxic, is set by the partial pressure of oxygen alone.
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a 20.00-ml sample of 0.150 m nh3 is being titrated with 0.200 m hcl. what is the ph after 15.00 ml of hcl has been added? kb of nh3
8.96 is the pH after 15.00 ml of hcl has been added.
What is pH?
The H+ ion concentration's negative logarithm is known as pH
We are aware that not every acid or base reacts with a chemical substance at the same pace. Other people respond extremely strongly, some people mildly, and some people don't react at all. We utilise a universal indicator that exhibits various colours at various concentrations of hydrogen ions in solution to objectively assess the strength of acids and bases
0 mL of NaOH has not been added, leaving a pH of 2.32.
Only HCOOH is present in the solution prior to the addition of any NaOH. The balance of the HCOOH in solution controls pH.
Ka = HCOO- concentration times H3O+ concentration divided by HCOOH concentration
8.96 is the pH after 15.00 ml of hcl has been added.
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A compound is found to have an empirical formula of ch2o. what is the molecular formula when the molecular weight is 180.0 grams?
The molecular formula is C₂H₄O₂ when molecular weight is 180 g having empirical formula of CH₂O.
The compound's empirical formula is CH₂O, which contains two hydrogen atoms and one oxygen atom for every carbon atom.
CH₂O has a mass of 30 (=12+2*1+16).The molecule has a molecular weight of about 180.As a result, the supplied molecule has the molecular formula C₆H₁₂O₆.
What is the chemical structure of the equation for water, CH₂O?
A substance that is organic and has a molar mass pf 60 grams / mole as well as an empirical formula of CH₂O also has a molecular formula or C₂H₄O₂.
How much CH₂O is in a mole?
A mol of CH₂O has a molar mass of 30.026 g.
The periodic chart must first be used to estimate its atomic mass of the each element in the compound.
Therefore, the molecular formula is C₂H₄O₂ with the empirical formula of CH₂O.
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How does changing the shape of an elastic object increase potential
energy?
the ph of a saturated solution of the metal hydroxide m(oh)2 is 11.15. calculate ksp for this compound.
Polar solute dissolve in polar solvent and non polar solute dissolve in non polar solvent. Therefore, Ksp for copper (II) hydroxide is 1.58x10⁻¹³.
What is solubility?Solubility shows the extent of solubility of a solute in solvent to make a solution. Solute is substances that is present in small amount. solvent is a substance that is present in large amount. Its SI unit is gram per litre or g/L.
Bond strength affect the solubility of a solute in solvent. weaker the bond strength is, more the solubility is. The weaker bond can be easily broken by water molecule.
pH= -log[H⁺]= 11.15
[H⁺]=7.07×10⁻¹²
[H⁺]×[OH⁻]=10⁻¹⁴
[OH⁻]=10⁻¹⁴÷7.07×10⁻¹²
=0.141×10⁻²
=0.00141M
M(OH)[tex]_2[/tex][tex]\rightarrow[/tex]M+²+ 2OH⁻
Initial concentration(M) 0 0
Change in concentration(M)| +S +2S
Equilibrium concentration(M)| S 2S
Ksp = [ Cu+² ] [ OH⁻] ²
=(S)(2S)²
=4S³
S= 3.41x10⁻⁵ g/L
Substituting the values, we get
Ksp =4(3.41x10⁻⁵)³
=158.6x10⁻¹⁵
=1.58x10⁻¹³
Therefore, Ksp for copper (II) hydroxide is 1.58x10⁻¹³.
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draw a structural formula for the major organic product of the following sn1 reaction.
For the post-obit, the Sn1 reaction, depicts the major organic product, identifies the nucleophile, substrate, and leaving grouping, and decides the rate-limiting step.
As shown in the diagram for the following Sn1 reaction, draw the major organic product, identify the nucleophile, substrate, and leaving grouping, and determine the rate-limiting steps.
Select the argument that properly identifies the reaction nucleophile, substrate, and leaving group. (CH3)2COH is the substrate, HCl (hydrochloric acid) is the nucleophile, and OH is the leaving group. (CH3)3COH is the substrate in the reaction, Cl is the nucleophile, and H20 is the leaving group in this reaction.
(CH3)3COH is the substrate, CF is the nucleophile, and OH is the leaving group in the reaction. The charge per unit limiting footsteps.
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Entropy never decreases in a spontaneous process. give an example to support this statement.
The entropy of the system of bodies increases during the spontaneous process of heat being transferred from colder to hotter bodies.
Entropy-Entropy is a measure for energy quality, with a lower value indicating higher quality. Lower entropy energy is energy that has been precisely organized. Chaotic energy storage results in high entropy.
Since every particle and atomic structure accelerates through time and space, entropy is constantly increasing. The second law of thermodynamics results in expressions with inequalities. Entropy cannot be destroyed by any means, at any scale, and thus cannot decrease overall.Entropy is created everywhere and always, increasing overall entropy at any scale, including life processes, open systems, micro-fluctuations, gravity, and entanglement.
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What percentage of a radioactive element will be left after 2 half-life?
25 percentage of a radioactive element will be left after 2 half-life time.
Time = n × t 1/2
After 1 half time time there will be 50 % original isotope and 50% of decay product. After 2 half time 25 % of original isotope and 75 % of decay product is there.
A quantity (of substance half-life )'s (symbol t12) is the amount of time needed for it to decrease to half of its original value. The phrase is frequently used in nuclear physics to refer to how long stable atoms last or how quickly unstable atoms decay radioactively. In a broader sense, the phrase is used to describe any exponential decay (or, very rarely, a non-exponential decay). For instance, the biological half-life of medications and other substances in the human body is discussed in the medical sciences. In exponential growth, doubling time is the opposite of half-life. A characteristic unit for the exponential decay equation, half-life is constant during the course of an exponentially decaying quantity's lifetime. The table below illustrates how a quantity decreases in relation to the number.
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22. consider two organic molecules, ethanol and benzene. one dissolves in water and the other does not. why?
Ethanol contains a polar O-H Bond, and benzene does not. Ethanol C2H6O and Benzene C6H6
What is Benzene?
The simplest organic, aromatic hydrocarbon is benzene. One of the basic petrochemicals and a naturally occurring component of crude oil is benzoene. It is a colourless liquid with a smell that is similar to gasoline. The chemical benzene is very poisonous and carcinogenic. It is mostly employed in the manufacture of polystyrene.
Although benzene is a material that is formed naturally by volcanoes and forest fires and found in many plants and animals, it is also a significant industrial chemical that is manufactured from coal and oil. In its purest form, benzene is a transparent liquid without any color.
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Is argon a gas at room temperature and pressure?
The noble gases of Group 8A argon a gas at room temperature and pressure at room temperature (as the name of the group implies); since they are all unreactive, monatomic elements, their boiling points are extremely low.
The noble gases are, in decreasing order of mass, helium, argon, krypton, xenon, and radon. Since they are so magnificent and don't generally react with anything, they are known as noble gases. Because of this, they are also referred to as inert gases. Noble gases are distinct because, at normal temperature, they are gaseous. The least reactive element, they. Most of the time, they do not mix with other atoms. The noble gases are a group of chemical elements that share many characteristics. They are all monatomic, odourless, colourless gases with very little chemical reactivity under normal conditions. Historically, the term "noble gases" also applied to inert gases.
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how many moles of hno3hno3 are present if 0.180 molmol of ba(oh)2ba(oh)2 was needed to neutralize the acid solution?
The moles of hno3 are present if 0.180 molmol of ba(oh)2 was needed to neutralize the acid solution is 0.36 mole of HNO₃.
Neutralization or neutralisation is a chemical reaction in which acid and a base react quantitatively with each other. In a reaction in water, neutralization outcomes in there being no excess of hydrogen or hydroxide ions gift inside the answer.
Calculation:-
Valance factor of HNO₃ is = 1
valance factor of Ba(OH)₂ is = 2
mole of Ba(OH)₂ is = 0.180
therefore mole oh HNO₃ neede is = 2 * 0.180
= 0.36 mole of HNO₃
Neutralisation is a chemical response wherein an acid and a base react with each different quantitatively. it's also written as Neutralisation. The acid electricity of the reactant gives the pH of the neutralised solution.
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what relative masses of dimethyl amine and dimethyl ammonium chloride do you need to prepare a buffer solution of ph
For dimethylamine:
Acidity (pKa) 10.64
Basicity (pKb) 3.36
What is Buffer Solution?
The buffer solution, a water-based solvent solution, is created by combining a weak acid and its conjugate base, or a weak base and its conjugate acid. They can be diluted or have small amounts of acid or alkali added to them without the pH of the solution altering.
The pH of buffer solutions scarcely changes when a modest quantity of a strong acid or strong base is introduced. They are therefore used to keep the pH level constant.
Consider this for a moment: If the molar ratio of dimethylamine to dimethylammonium chloride were 1:1, pH would be equal to pKa. At that point, you would be at the half-equivalence point. 10.64 would be the pH.
However, you need a buffer whose pH is 10.43. A molar excess of dimethylammonium chloride must thus exist.
Applying the H-H equation
pH equals pKa plus log ([[base]/[salt]])
10.43 = 10.64 + log ([base[/salt]) log ([base[/salt]) = 10-43 - 10.64 log ([base]/[salt]) = -0.21 log ([base]/[salt]) = 10-0.21 log ([base]/[salt]) = 0.62
The buffer has to be made by combining 1.0mol of dimethylammonium chloride and 0.62mol of dimethylamine.
Mass to volume as necessary:
Dimethylammonium chloride, molar mass 81.55g/mol
Molar mass of dimethylamine is equal to 45.08g/mol minus 0.62mol, or 27.95g.
Dimethylamine to dimethylammonium chloride mass ratio is 81.55 to 27.95.
OR Ratio is 2.92:1.0 (81.55/27.95).
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How many single bonds are in CH2O?
this is a chemical process in autotrophs that uses light energy to create chemical energy.
Photosynthesis is a process that occurs in autotrophs, or organisms that can produce their own food. This process uses light energy from the sun to convert carbon dioxide and water into glucose and oxygen. This process is vital for life on Earth, as it is the primary source of energy for many organisms.
Photosynthesis: a chemical process that uses lightPhotosynthesis is a chemical process that occurs in autotrophs, or organisms that can produce their own food. This process uses light energy from the sun to convert carbon dioxide and water into glucose and oxygen. The light energy is absorbed by specialized molecules called chlorophyll, which then use the energy to catalyze the conversion of carbon dioxide and water into glucose and oxygen. Photosynthesis is vitally important, as it is the primary source of energy for many organisms and is essential for life on Earth. In addition, photosynthesis provides oxygen to the atmosphere, which is used by other organisms. Without photosynthesis, the Earth would be a very different, much less hospitable place.
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Which transition metals are paramagnetic but can easily form ferromagnetic alloys with other metals? Question 17 options: A) Transition metals in groups 1-5, periods 5 and 6 B) Transition metals in groups 11 and 12, periods 4 and 5 C) Transition metals in groups 8-10, periods 4 and 5 D) Transition metals in groups 8-10, periods 5 and 6
The transition metals that are paramagnetic but can easily form ferromagnetic alloys with other metals are Iron, Cobalt, and Nickel.
Hence, the correct option is C: Transition metals in groups 8-10, periods 4 and 5.
What are paramagnetic and ferromagnetic substances?Paramagnetic substances are substances that are weakly attracted to magnets. The atoms of paramagnetic substances contain electrons that mostly spin in the same direction. They include aluminum, gold, and copper.
Ferromagnetic substances are substances that are strongly attracted to magnets when placed near magnets. They include metals such as Iron, Cobalt, and Nickel.
Transition metals are metals that have partially filled D-orbitals. Hence, transition metals are paramagnetic as well as ferromagnetic.
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Answer: C) Transition metals in groups 8-10, periods 4
Explanation:
Which air mass would show the most dramatic change in both temperature and moisture content as it moves over a large body of very warm water?
Continental polar (cP) or continental arctic (cA) air masses are cold, dry, and stable.
These air masses originate over northern Canada and Alaska as a result of radiational cooling.
They move southward, east of Rockies into the Plains, then eastward. air mass would show the most dramatic change in both temperature and moisture content as it moves over a large body of very warm water
What does air mass cP mean?
The same arctic air mass will pick up some of the heat from the earth if it goes south from Canada into the southern U.S., but it will stay quite dry due to a lack of moisture. A continental polar air mass is what this is (cP).
During the winter, a continental polar air mass can develop over the land. It comes from northern Canada or Alaska in the Northern Hemisphere. It transports dry weather to the United States as it goes south.
Cp. In a system, Cp is the quantity of heat energy that is emitted or absorbed by a unit mass of the substance with a change in temperature at a constant pressure. It is the transmission of heat energy between a system and its surroundings under constant pressure, to put it another way.
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what is the concept of half-life with respect to radioactive nuclides? what rate law is characteristic of radioactivity? libretext
The amount of time it takes for half of the radioactive atoms present to decay is known as the radioactive half-life. When a radioisotope changes into another radioisotope, the process is known as radioactive decay, and radiation of some kind is released. The integrated first-order rate law describes radioactivity.
Are first order reactions involved in radioactivity?First-order reactions include those in radioactive decay. The rate of decay, also known as activity, of a sample of a radioactive substance is the decrease in radioactive nuclei per unit of time.
What is the first order reaction's integrated rate law?The integrated rate rule for the first-order reaction A's products is ln[A] t = -kt + ln[A] 0. An illustration of the natural log of [A] as a function of time is given since this equation has the form y = mx + b.
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(a) an ideal gas occupies a volume of 1.0 cm3 at 20oc and atmospheric pressure. determine the number of molecules of gas in the container. (b) if the pressure of the 1.0 cm3 volume is reduced to 1.0 x 10-11 pa (an extremely good vacuum) while the temperature remains constant, how many moles of gas remain in the container?
(a) The number of molecules of gas in the container will be 4.1583 x 10⁻⁵ moles
(b) The moles of gas remaining in the container will be 1.231482x 10⁻²⁰ moles
For a
Volume of gas = 1.0 x 10⁻⁶ m³
Temperature of gas = 20 °C or 293 K
Pressure = 1.013 x 10⁵ Pa
R = 8.3143 J/mol.K
We will calculate the number of molecules from the ideal gas equation.
PV = nRT
Rearrange the equation for the number of moles
n= PV / RT
Put the values
n = (1.013 x 10⁵ Pa) (1.0x10⁻⁶ m³) / ((8.3143 J/mol.K) (293 K))
n = 4.1583 x 10⁻⁵ moles
For b
Volume of gas = 1.0 x 10⁻⁶ m³
Temperature of gas = 20 °C or 293 K
Pressure = 1.0 x 10⁻¹¹ pa
We will calculate the number of moles from the ideal gas equation.
PV = nRT
Rearrange the equation for the number of moles
n = PV / RT
n = (3.0 x 10⁻¹¹ Pa) (1.0 x 10⁻⁶ m³) / (8.3143 J/mol.K) (293 K)
n = 1.231482 x 10⁻²⁰ mol
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b) if the initial rate of appearance of xef4 is 2.50 x10-2 atm/min, what is the rate of disappearance of xe?
The rate of disappearance of xe is 2.50×10-² atm/min.
What is rate of disappearance?
The rate of disappearance can be defined as the speed at which a reactant dissipates after being consumed in the process of the reaction.
2.50×10-² atm/min is the rate of disappearance of xenon(xe), if the initial rate of appearance of xef4 is 2.50 x 10^-2 atm/min
xe+ 2F2⇒ xef4
rate of disappearance of xe= 1( rate of disapperance of xe)
= 1( initial rate of appearance of xef4)
⇒1x= 2.50×10-² atm/min
⇒rate of disappearance of xe= 2.50×10-² atm/min
Therefore, the rate of disappearance of xe is 2.50×10-² atm/min.
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the chelate effect describes the increased affinity for a polydentate ligand versus a ligand of lower denticity. consider the reaction considering the bonds formed and bonds broken in the reaction, what is the sign of enthalpy change in this reaction?
Entropy (+ S) increases noticeably when monodentate ligands are replaced by chelating ligands. This is what the Chelate Effect is mostly caused by.
To give one example, the total number of molecules rises from two to three when en takes the place of two ammonia ligands .Just one more molecule is all that is required to accelerate the reaction.
In the aforementioned example, there is only one bidentate ligand in play. The chelate action is further amplified when numerous bidentate ligands are involved or when denticity rises. Think about the two complexation equilibria between ammonia, NH3, and the cobalt (II) ion, Co2+(aq), ethylenediamine (en), on the one hand, and the cobalt (II) ion, Co2+(aq) and en.
the entropy caused by an increase or decrease in the number of freely moving molecules. The number of free molecules in the system rises when a chelating ligand takes the place of multiple monodentate ligands, leading to a sizable increase in entropy. The chelate effect is primarily driven by this energy component.
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